Sulfur/Galena/Calcite

Object/Artifact

-

Crater Rock Museum

Name/Title

Sulfur/Galena/Calcite

Entry/Object ID

2004.1.170

Description

Assemblage Zone: pegmatite dikes Chemical Composition: S , Elemental Sulfur Crystal System: Orthorhombic System Description: Common Name: Sulfur / Galena / Calcite Chemistry: S , Elemental Sulfur / PbS Lead Sulfide / CaCo3 Carbonates Location: Unknown Description: Yellow-green colored crystalline sulfur 'fuzz' on surface of generally-amorphous galena (with some tiny crystals) that is interspersed with opaque white calcite crystals. PHYSICAL CHARACTERISTICS OF SULFUR: Color is a strong yellow color in thick crystals and duller yellow in small crystals to pale yellow in massive or powdery forms. Can also be reddish or greenish yellow with impurities. Luster is vitreous to more often resinous or earthy in massive forms. Transparency is transparent to translucent. Crystal System is orthorhombic; 2/m 2/m 2/m Crystal Habits include mostly massive or powdery forms but well shaped blocky crystals are common. Crystals can be made up of two dipyramids, one with steeper faces than the other, prisms and/or pinacoids in various combinations. Cleavage is very poor in two directions. Fracture is conchoidal. Streak is yellow. Hardness is 2. Specific Gravity is 2.0 - 2.1 (well below average) Associated Minerals are celestite, calcite, aragonite and gypsum. Other Characteristics: odor (see above), poor heat conductivity makes it brittle when heated and can actually crack if held tightly in a person's hand.e. Best Field Indicators are color, odor, heat sensitivity, lack of good cleavage and crystal habit PHYSICAL CHARACTERISTICS OF GALENA; Color is lead to silver gray sometimes with a bluish tint. Luster is metallic to dull in weathered faces. Transparency crystals are opaque. Crystal System is isometric; 4/m bar 3 2/m Crystal Habits include the cube, octahedron and combinations of the two. Spinel twinning is possible forming flattened crystals. Also massive and granular. Cleavage is perfect in four direction forming cubes. Fracture is uneven and rarely seen because of the perfect cleavage. Hardness is 2.5+ Specific Gravity is approximately 7.5+ (heavy even for metallic minerals) Streak is lead gray Associated Minerals are calcite, dolomite, sphalerite, pyrite and other sulfide minerals, also lead oxidation minerals such as cerussite and anglesite. Other Characteristics: brighter metallic luster on cleavage surfaces than on crystal faces. Best Field Indicators are crystal habit, cleavage and, perhaps most importantly, density. PHYSICAL CHARACTERISTICS OF CALCITE: Color is extremely variable but generally white or colorless or with light shades of yellow, orange, blue, pink, red, brown, green, black and gray. Occasionally iridescent. Luster is vitreous to resinous to dull in massive forms. Transparency: Crystals are transparent to translucent. Crystal System is trigonal; bar 3 2/m Crystal Habits are extremely variable with almost any trigonal form possible. Common among calcite crystals are the scalenohedron, rhombohedron, hexagonal prism, and pinacoid. Combinations of these and over three hundred other forms can make a multitude of crystal shapes, but always trigonal or pseudo-hexagonal. Twinning is often seen and results in crystals with blocky chevrons, right angled prisms, heart shapes or dipyramidal shapes. A notch in the middle of a doubly terminated scalenohedron is a sure sign of a twinned crystal. lamellar twinning also seen resulting in striated cleavage surfaces. Pseudomorphs after many minerals are known, but easily identified as calcite. Also massive, fibrous, concretionary, stalactitic, nodular, oolitic, stellate, dendritic, granular, layered, etc. etc. Cleavage is perfect in three directions, forming rhombohedrons. Fracture is conchoidal. Hardness is 3 (only on the basal pinacoidal faces, calcite has a hardness of less than 2.5 and can be scratched by a fingernail). Specific Gravity is approximately 2.7 (average) Streak is white. Other Characteristics: refractive indices of 1.49 and 1.66 causing a significant double refraction effect (when a clear crystal is placed on a single line, two lines can then be observed), effervesces easily with dilute acids and may be fluorescent, phosphorescent, thermoluminescence and triboluminescent. Associated Minerals are numerous but include these classic associations: Fluorite, quartz, barite, sphalerite, galena, celestite, sulfur, gold, copper, emerald, apatite, biotite, zeolites, several metal sulfides, other carbonates and borates and many other minerals. . Best Field Indicators are crystal habit, reaction to acid, abundance, hardness, double refraction and especially cleavage. Fracture: conchoidal Hardness: 2 Gypsum Luster: Vitreous Occurrence: Elemental sulfur can be found near hot springs and volcanic regions in many parts of the world, especially along the Pacific Ring of Fire. Such volcanic deposits are currently mined in Indonesia, Chile, and Japan. Sicily is also famous for its sulfur mines. Sulfur deposits are polycrystalline, and the largest documented single crystal measured 22x16x11 cm3.[13][14] Significant deposits of elemental sulfur also exist in salt domes along the coast of the Gulf of Mexico, and in evaporites in eastern Europe and western Asia. The sulfur in these deposits is believed to come from the action of anaerobic bacteria on sulfate minerals, especially gypsum, although apparently native sulfur may be produced by geological processes alone, without the aid of living organisms (see below). However, fossil-based sulfur deposits from salt domes are the basis for commercial production in the United States, Poland, Russia, Turkmenistan, and Ukraine. Sulfur production through hydrodesulfurization of oil, gas, and the Athabasca Oil Sands has produced a surplus — huge stockpiles of sulfur now exist throughout Alberta, Canada. Common naturally occurring sulfur compounds include the sulfide minerals, such as pyrite (iron sulfide), cinnabar (mercury sulfide), galena (lead sulfide), sphalerite (zinc sulfide) and stibnite (antimony sulfide); and the sulfates, such as gypsum (calcium sulfate), alunite (potassium aluminium sulfate), and barite (barium sulfate). It occurs naturally in volcanic emissions, such as from hydrothermal vents, and from bacterial action on decaying sulfur-containing organic matter. The distinctive colors of Jupiter's volcanic moon, Io, are from various forms of molten, solid and gaseous sulfur. There is also a dark area near the Lunar crater Aristarchus that may be a sulfur deposit. Sulfur is present in many types of meteorites. Ordinary chondrites contain on average 2.1% sulfur, and carbonaceous chondrites may contain as much as 6.6%. Sulfur in meteorites is normally present entirely as troilite (FeS), but other sulfides are found in some meteorites, and carbonaceous chondrites contain free sulfur, sulfates, and possibly other sulfur compounds .Notable Occurrences include Michigan and Ohio, USA; Sicily; Poland and Chil Galena is found in lead sulfide ore veins, and disseminated in igneous and sedimentary rocks. Calcite is a common constituent of sedimentary rocks, limestone in particular, much of which is formed from the shells of dead marine organisms. Approximately 10% of sedimentary rock is limestone. Calcite is the primary mineral in metamorphic marble. It also occurs as a vein mineral in deposits from hot springs, and it occurs in caverns as stalactites and stalagmites. Calcite may also be found in volcanic or mantle-derived rocks such as carbonatites, kimberlites, or rarely in peridotites. Lublinite is a fibrous, efflorescent form of calcite. Calcite is often the primary constituent of the shells of marine organisms, e.g., plankton (such as coccoliths and planktic foraminifera), the hard parts of red algae, some sponges, brachiopoda, echinoderms, most bryozoa, and parts of the shells of some bivalves, such as oysters and rudists). Calcite is found in spectacular form in the Snowy River Cave of New Mexico as mentioned above, where microorganisms are credited with natural formations. Trilobites, which are now extinct, had unique compound eyes. They used clear calcite crystals to form the lenses of their eyes. Notable Occurrences include Pugh Quarry, Ohio; Rosiclare, Illinois; Franklin, New Jersey; Elmwood, Tennessee; Brush Creek and other Missouri, Wisconsin, Kansas and Oklahoma localities, USA; Andreasburg, Harz Mountains and Saxony, Germany; Brazil; Guanajuato, Mexico; Cornwall, Durham and Lancashire, England; Bombay area of India; Eskifjord, Iceland; many African localities as well as others around the world with their own unique varieties. Rock Type: Sedimentary Specific Gravity: 2-2.1 Streak: yellow Variety: Sulfur (spelled sulphur in some countries) can make a very beautiful mineral specimen, and fine quality examples are much sought after. The unmistakable deep yellow color is not matched by any other mineral and the nicely shaped crystal forms of sulfur add to its attractiveness. Galena's characteristic cubes, distinctive cleavage and high density make it easy to identify and a favorite in high school geology labs. The structure of Galena is identical to that of halite, NaCl. The two minerals have the same crystal shapes, symmetry and cleavage. Some Galena may contain up to 1% silver in place of lead. The large volume of Galena that is processed for lead produces enough Silver as a by product to make Galena the leading ore of Silver. There are several varieties of Calcite and it would be impossible to describe them all. However there are a few standouts. Possibly the most well known of calcite's varieties is its most common form, the classic scalenohedron or "Dogtooth Spar" as it is sometimes called. This variety appears as a double pyramid or dipyramid, but is actually a distinctly different form. The point of the scalenohedron is sharp and resembles the canine tooth of a dog, hence the name. Beautiful clear colorless or amber-orange examples of this variety are considered classics and outstanding examples come from Pugh Quarry, Ohio; Cornwall, England and Elmwood, Tennessee but the variety is found worldwide. Not necessarily a variety of calcite, cave formations are certainly a unique aspect of calcite's story. Calcite is the primary mineral component in cave formations. Stalactites and stalagmites, cave veils, cave pearls, "soda straws" and the many other different cave formations that millions of visitors to underground caverns enjoy are made of calcite. It is the fact that calcite is readily dissolved that these formations occur. Overlying limestones or marbles are dissolved away by years and years of slightly acidic ground water to percolate into the caverns below. In fact the caverns themselves may have been the result of water dissolving away the calcite rich rock. As the calcite enriched water enters a relatively dry cavern, the water starts to evaporate and thus precipitate the calcite. The resulting accumulations of calcite are generally extremely pure and are colored if at all, by very small amounts of iron or other impurities. Mexican onyx is a variety of calcite that is used extensively for ornamental purposes. It is carved into figurines and is so popular that almost every child in the USA owns a small onyx animal or two. Carvings such as vases, bookends, plates, eggs, obilisks, pyramids and statues are all popular. It is not the same onyx as the quartz variety of onyx which is a little more precious (it is used in jewelry) and is banded white and black. To avoid confusion it is best to refer to it as Mexican Onyx. Mexican onyx is banded with multiple orange, yellow, red, tan, brown and white colors that have marble-like texture. The carvings are quite attractive and affordable; a rare combination! Another variety is the so called "Iceland Spar", which is basically clear cleaved fragments of completely colorless (ice-like) calcite. Originally discovered and named after Eskifjord, Iceland where the calcite is found in basalt cavities. In rock shops around the world, iceland spar is available in large quantities and at affordable prices and are popular among children. Most of today's iceland spar comes from Mexico. The iceland spar displays the classic cleavage form of calcite, the rhombohedron. Iceland spar was and is used for optical equipment and during World War II it was a strategic mineral as it was used for the sighting equipment of bombardiers and gunners. It is iceland spar that best demonstrates the unique property of calcite called double refraction.

Collection

Suomynona Mineral Collection

Acquisition

Accession

2004.1

Source or Donor

Suomynona Mineral Collection

Acquisition Method

Donation

Dimensions

Width

1-1/2 in

Depth

1 in

Length

2 in

Dimension Notes

Dimension taken at widest points

Location

Location

Container

Right

Drawer

2nd Shelf

Shelf

Left

Cabinet

F7

Wall

North

Building

Founders Room

Category

Permanent